REPOZITORIU UPSC

Compuși hetero-bimetalici ai Ba(II) ce conțin ligand O,N,O-donor și anion [Co(NCS)4] 2-

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dc.contributor.author URECHE, Dumitru
dc.contributor.author BULHAC, Ion
dc.contributor.author BOUROȘ, Pavlina
dc.date.accessioned 2023-05-04T09:37:26Z
dc.date.available 2023-05-04T09:37:26Z
dc.date.issued 2023-03-18
dc.identifier.citation URECHE, Dumitru, BULHAC, Ion, BOUROȘ, Pavlina. Compuși hetero-bimetalici ai Ba(II) ce conțin ligand O,N,O-donor și anion [Co(NCS)4] 2. În: Conferința științifico-practică internațională „Instruire prin cercetare pentru o societate prosperă”, Ediția a-X-a, 18-19 martie 2023. Vol. 1: Realizări contemporane în științe ale naturii. Chişinău: CEP UPSC, 2023, pp. 50-52. ISBN 978-9975-46-716-2. ISBN 978-9975-46-717-9 (Vol. 1). en_US
dc.identifier.isbn 978-9975-46-716-2
dc.identifier.isbn 978-9975-46-717-9
dc.identifier.uri http://dir.upsc.md:8080/xmlui/123456789/4652
dc.description.abstract The reaction between pyridine-2,6-dicarbonyl dichloride and barium(II) and cobalt(II) thiocyanates in the methanol/ethanol environment result in two hetero-bimetallic compounds were obtained, which differ fundamentally: the compound obtained in methanol is a molecular compound with the formula [BaCoL13(μ-NCS)2(NCS-κN)2] (1) (L1 - dimethylpyridine-2,6-dicarboxylate ester), and the one obtained in ethanol is one of ionic nature with the formula [BaL24][Co(NCS)4] (2) (L2 – diethylpyridine-2,6-dicarboxylate ester). The complexes were investigated by X-ray and IR spectroscopy methods. en_US
dc.language.iso ro en_US
dc.publisher Universitatea Pedagogică de Stat "Ion Creangă" en_US
dc.subject Hetero-bimetallic compounds en_US
dc.subject Ba(II) en_US
dc.subject Co(II) en_US
dc.subject Dialkylpyridine-2 en_US
dc.subject 6-dicarboxylate en_US
dc.title Compuși hetero-bimetalici ai Ba(II) ce conțin ligand O,N,O-donor și anion [Co(NCS)4] 2- en_US
dc.title.alternative Hetero-bimetallic compounds of Ba(II) containing O,N,O-donor ligand and [Co(NCS)4] 2- anion en_US
dc.type Article en_US


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